Insight into the Mechanism of the CuAAC Reaction by Capturing the Crucial Au

Authors :: Yaping, Fang
Kang, Bao
Peng, Zhang
Hongting, Sheng
Yapei, Yun
Shu-Xian, Hu
Didier, Astruc
Manzhou, Zhu
Source :: Journal of the American Chemical Society. 143(4)
Publication Year :: 2021
Abstract: The classic Fokin mechanism of the CuAAC reaction of terminal alkynes using a variety of Cu(I) catalysts is well-known to include alkyne deprotonation involving a bimetallic σ,π-alkynyl intermediate. In this study, we have designed a CNT-supported atomically precise nanocluster Au

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