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Synthesis and structure of 16 pi octaalkyltetraphenylporphyrins
- Source :
- Journal of the American Chemical Society. 127(42)
- Publication Year :
- 2005
-
Abstract
- The oxidized octaethyltetraphenylporphyrin (1, OETPP) and the corresponding newly prepared octaisobutyltetraphenylporphyrin (3, OisoBuTPP) could be isolated from the reaction of OETPPLi2 (or OisoBuTPPLi2) with SOCl2. The X-ray analysis and the characteristic UV-vis spectra of 1 and 3 revealed that these are the first examples of 16 pi nonaromatic porphyrins.
- Subjects :
- Models, Molecular
Porphyrins
Molecular Structure
Crystallography, X-Ray
Subjects
Details
- ISSN :
- 00027863
- Volume :
- 127
- Issue :
- 42
- Database :
- OpenAIRE
- Journal :
- Journal of the American Chemical Society
- Accession number :
- edsair.pmid..........4e59ba2f6464822a6306ff6114202d00