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Diaqua-bis-(5-carb-oxy-2-propyl-1H-imidazole-4-carboxyl-ato-κN,O)cadmium N,N-dimethyl-formamide disolvate

Authors :
Shao-Wei, Tong
Shi-Jie, Li
Wen-Dong, Song
Dong-Liang, Miao
Jing-Bo, An
Source :
Acta Crystallographica Section E: Structure Reports
Publication Year :
2011

Abstract

In the title complex, [Cd(C(8)H(9)N(2)O(4))(2)(H(2)O)(2)]·2C(3)H(7)NO, the six-coordinate Cd(II) ion is in a slightly distorted octa-hedral environment, defined by two O atoms from two coordinated water mol-ecules and two carboxyl-ate O atoms and two N atoms from two N,O-bidentate 5-carb-oxy-2-propyl-1H-imidazole-4-carboxyl-ate ligands. In the crystal, complex mol-ecules and dimethyl-formamide solvent mol-ecules are linked by O-H⋯O and N-H⋯O hydrogen bonds into a two-dimensional supra-molecular structure. The propyl groups of the ligands are disordered over two conformations with refined occupancies of 0.680 (7) and 0.320 (7).

Subjects

Subjects :
Metal-Organic Papers

Details

ISSN :
16005368
Volume :
67
Issue :
Pt 12
Database :
OpenAIRE
Journal :
Acta crystallographica. Section E, Structure reports online
Accession number :
edsair.pmid..........3701a0129a11db61f431d2c81363d1e6