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Diaqua-bis-(5-carb-oxy-2-propyl-1H-imidazole-4-carboxyl-ato-κN,O)cadmium N,N-dimethyl-formamide disolvate
- Source :
- Acta Crystallographica Section E: Structure Reports
- Publication Year :
- 2011
-
Abstract
- In the title complex, [Cd(C(8)H(9)N(2)O(4))(2)(H(2)O)(2)]·2C(3)H(7)NO, the six-coordinate Cd(II) ion is in a slightly distorted octa-hedral environment, defined by two O atoms from two coordinated water mol-ecules and two carboxyl-ate O atoms and two N atoms from two N,O-bidentate 5-carb-oxy-2-propyl-1H-imidazole-4-carboxyl-ate ligands. In the crystal, complex mol-ecules and dimethyl-formamide solvent mol-ecules are linked by O-H⋯O and N-H⋯O hydrogen bonds into a two-dimensional supra-molecular structure. The propyl groups of the ligands are disordered over two conformations with refined occupancies of 0.680 (7) and 0.320 (7).
- Subjects :
- Metal-Organic Papers
Subjects
Details
- ISSN :
- 16005368
- Volume :
- 67
- Issue :
- Pt 12
- Database :
- OpenAIRE
- Journal :
- Acta crystallographica. Section E, Structure reports online
- Accession number :
- edsair.pmid..........3701a0129a11db61f431d2c81363d1e6