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catena-Poly[silver(I)-μ-acridine-9-carboxyl-ato-κN:O,O']

Authors :
Ya-Qing, Yang
Xiao-Ye, Chen
Shu-Min, Huo
Yan-Ru, Ma
Rong-Hua, Zeng
Source :
Acta Crystallographica Section E: Structure Reports
Publication Year :
2010

Abstract

In the title coordination polymer, [Ag(C(14)H(8)NO(2))](n), the Ag(I) cation is coordinated by two O atoms and one N atom from two symmetry-related acridine-9-carboxyl-ate ligands in a distorted trigonal-planar geometry. The metal atoms are connected by the ligands to form chains running parallel to the b axis. π-π stacking inter-actions [centroid-to-centroid distances 3.757 (2)-3.820 (2) Å] and weak Ag⋯O inter-actions further link the chains to form a layer network parallel to the ab plane. The Ag(I) cation is disordered over two positions, with refined site-occupancy factors of 0.73 (3):0.27 (3).

Subjects

Subjects :
Metal-Organic Papers

Details

ISSN :
16005368
Volume :
66
Issue :
Pt 11
Database :
OpenAIRE
Journal :
Acta crystallographica. Section E, Structure reports online
Accession number :
edsair.pmid..........1af731048102d2957bd4f8e6f355f991