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SO
- Source :
- Chemical communications (Cambridge, England). 56(88)
- Publication Year :
- 2020
-
Abstract
- The atmospheric reaction of OH radicals with dimethyl disulfide, CH3SSCH3, proceeds primarily via OH addition forming CH3S and CH3SOH as reactive intermediates, and to a lesser extent via H-abstraction resulting in the peroxy radical CH3SSCH2OO in the presence of O2. The latter undergoes a fast two-step isomerization process leading to HOOCH2SSCHO. CH3S and CH3SOH are both converted to SO2 and CH3O2 with near unity yields under atmospheric conditions.
Details
- ISSN :
- 1364548X
- Volume :
- 56
- Issue :
- 88
- Database :
- OpenAIRE
- Journal :
- Chemical communications (Cambridge, England)
- Accession number :
- edsair.pmid..........02c58b596bf86a5bf27839e81599b748