Physico-chemical characterization of seaborgium as oxide hydroxide

Authors :: Hübener, S.
Taut, S.
Vahle, A.
Dressler, R.
Eichler, B.
Gäggeler, H. W.
Jost, D.
Piguet, D.
Türler, A.
Schädel, M.
Jäger, E.
Brüchle, W.
Schimpf, E.
Kirbach, U.
Trautmann, N.
Yakushev, A.
Source :: Radiochimica Acta 89 (2001) 737-741
Publication Year :: 2001
Abstract: Seaborgium (element 106) was studied in comparison with tungsten in the O2-H2O(g)/SiO2(s)-system using high-temperature on-line isothermal gas chromatography. The 21-s nuclide 266Sg was produced in the 248Cm + 22Ne reaction at a beam energy of 119 MeV. The reaction products were continuously transported by a He(MoO3)-jet to the chromatography apparatus HITGAS. Group 6 element oxide hy-droxide molecules volatile at temperatures above 1000 K were formed at 1325 K by adding humid oxygen as reactive gas. 266Sg was unambiguously detected after gas chromatographic separation by measuring 266Sg-262Rf mother-daughter a-sf correlations. The experimental results demonstrate the volatility of seaborgium in humid oxygen, presumably as seaborgium oxide hydroxide as typical for both uranium (VI) and the group 6 elements.