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Formation and trapping of the thermodynamically unfavoured inverted-hemicucurbit[6]uri
- Publication Year :
- 2019
- Publisher :
- Zenodo, 2019.
-
Abstract
- Research paper published inChem. Commun., 2019,55, 9307-9310 Abstract: Formation of inverted-cis-cyclohexanohemicucurbit[6]uril (i-cis-cycHC[6]), with up to 33% isolated yield, can be induced at the expense of thermodynamically favouredcis-cycHC[6]. Reaction selectivity is governed by the solution-based template-aided dynamic combinatorial chemistry and continuous precipitation of the formed macrocycles. Different binding affinities of three diastereomeric cycHC[6]s with trifluoroacetic acid is demonstrated.
Details
- Database :
- OpenAIRE
- Accession number :
- edsair.od......2659..56efc39d8540d85ae33fc13a024fecac