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Tunable Rh(I) Fischer carbene complexes for application in the hydroformylation of 1-octene
- Publication Year :
- 2020
- Publisher :
- Elsevier, 2020.
-
Abstract
- The preparation of a series of rhodium(I) complexes coordinated by various electronically tuneable Fischer carbene (FC) ligands, is reported. The Rh(I) metal complexes’ electronic properties could readily be modulated by variation of a p-N,N-dimethylaniline moiety with a ruthenocenyl substituent, or alternatively, substituting the carbene O-heteroatom for an amino-group. The electronic properties of the complexes were evaluated, and it was determined from the Tolman electronic parameters that the donor-ability of the FC ligands are comparable to N-heterocyclic carbenes. Furthermore, the facile control of the electronic properties of the complexes was demonstrated by mild oxidation of a ferrocenyl aminocarbene rhodium(I) complex, yielding the corresponding ferrocenium rhodium(I) complex cation. Finally, the complexes were evaluated as catalyst precursors for the hydroformylation of 1-octene.
Details
- Language :
- English
- Database :
- OpenAIRE
- Accession number :
- edsair.od......2423..9fe2e94c7e2e5a1488652746c0f8ceeb