[U(bipy)4]: A Mistaken Case of U0?

Authors :: Fortier, S
Veleta, J
Pialat, A
Le Roy, J
Ghiassi, KB
Olmstead, MM
Metta-Magaña, A
Murugesu, M
Villagrán, D
Source :: Fortier, S; Veleta, J; Pialat, A; Le Roy, J; Ghiassi, KB; Olmstead, MM; et al.(2016). [U(bipy)4]: A Mistaken Case of U0?. Chemistry-A European Journal, 22(6), 1931-1936. doi: 10.1002/chem.201504982. UC Davis: Retrieved from: http://www.escholarship.org/uc/item/7vn6235f
Publication Year :: 2016
Publisher :: eScholarship, University of California, 2016.
Abstract: © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. After more than 50 years, the synthesis and electronic structure of the first and only reported "U0complex" [U(bipy)4] (1) has been reinvestigated. Additionally, its one-electron reduced product [Na(THF)6][U(bipy)4] (2) has been newly discovered. High resolution crystallographic analyses combined with magnetic and computational data show that 1 and its derivative 2 are best described as highly reduced species containing mid-to-high-valent uranium ligated by redox non-innocent ligands.

Language :: English
Database :: OpenAIRE
Journal :: Fortier, S; Veleta, J; Pialat, A; Le Roy, J; Ghiassi, KB; Olmstead, MM; et al.(2016). [U(bipy)4]: A Mistaken Case of U0?. Chemistry-A European Journal, 22(6), 1931-1936. doi: 10.1002/chem.201504982. UC Davis: Retrieved from: http://www.escholarship.org/uc/item/7vn6235f
Accession number :: edsair.od.......325..0b06b4fbcd7bf2bb40a4589e3b591a74
Full Text :: https://doi.org/10.1002/chem.201504982.