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Homochiral Matching in the Diels-Alder Clyclodimerization 2-Vinyl-7-Oxabicyclo[2.2.1]Hept-2-Ene Derivatives

Authors :
Meerpoel, L.
Vrahami, M. M.
Ancerewicz, J.
Vogel, P.

Abstract

Racemic 6-vinyl-7-oxabicyclo[2.2.1]hept-5-en-2-one, 5-vinyl-7-oxabicyclo[2.2.1]hept-5-en-2-one and their ethylene acetals undergo highly stereoselective Diels-Alder cyclodimerizations. The optically pure semicyclic dienes give the corresponding optically pure dimers with the same ease.

Details

Database :
OpenAIRE
Accession number :
edsair.od.......185..89a1a9178abfeec36a195fd92615522f