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A [HN(BH=NH)2]2- Dianion, Isoelectronic with a β-Diketiminate
- Publication Year :
- 2018
- Publisher :
- American Chemical Society, 2018.
-
Abstract
- The 1:2 reaction of the Al(III) β-diketiminate dihydride [{DMPnacnac}AlH2] (DMPnacnac = HC{C(Me)N(2,6-Me2-C6H3)}2) (1) with ammonia-borane (NH3BH3) gives the new complex [{DMPnacnac}Al{NHBH)2NH}] (3), whose [HN(BHNH)2]2- dianion is isoelectronic with β-diketiminate anions.
- Subjects :
- 3402 Inorganic Chemistry
34 Chemical Sciences
Subjects
Details
- Database :
- OpenAIRE
- Accession number :
- edsair.od.......109..dfec35b33b254b17acadb7519d8d30b5