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Microwave induced 'egg yolk' structure in Cr/V-MIL-53

Authors :
Henk Vrielinck
Irena Nevjestic
Karen Leus
Hannes Depauw
Freddy Callens
Katrien Haustraete
An Verberckmoes
Guangbo Wang
Christophe Detavernier
Pascal Van Der Voort
Els De Canck
Jonatan De Winne
Source :
Chemical Communications. 53:8478-8481
Publication Year :
2017
Publisher :
Royal Society of Chemistry (RSC), 2017.

Abstract

Using a one pot microwave procedure, mixed-metal “egg yolk” MOFs are created, with a core of (Cr/V)-MIL-53 and a shell of Cr-MIL-53. In contrast, the solvothermal method produces homogeneous mixed-metal MOFs. The influence of Cr and V on the flexibility and breathing was studied via T-XRPD and CO2 adsorption measurements.

Details

ISSN :
1364548X and 13597345
Volume :
53
Database :
OpenAIRE
Journal :
Chemical Communications
Accession number :
edsair.doi.dedup.....fea6c84ab0b890bbb74f12bc8612a982
Full Text :
https://doi.org/10.1039/c7cc04651k