Uniformly Decorated Molybdenum Carbide/Nitride Nanostructures on Biomass Templates for Hydrogen Evolution Reaction Applications

Natural fibrils derived from biomass were used as a template to synthesize uniformly decorated nanoparticles (10–12 nm) of molybdenum carbide (Mo2C) and molybdenum nitride (Mo2N) supported on carbon. The nanoparticles have been synthesized through the carburization and nitridation of molybdenum on cotton fibrils, using a high-temperature solid-state reaction. The catalyst exhibits an onset potential of 110 mV and an overpotential of 167 mV to derive a cathodic current density of 10 mA cm–2. The electrocatalyst also demonstrates excellent long-term durability of more than 2500 cycles in acidic media with a Tafel slope value of 62 mV dec–1.