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Autoxidation catalysis with N-hydroxyimides: more-reactive radicals or just more radicals?
- Source :
- Physical chemistry chemical physics : PCCP. 9(6)
- Publication Year :
- 2007
-
Abstract
- A first-principles analysis reveals that the catalytic efficiency of nitroxyl radicals in alkane oxidations is not simply correlated with their reactivity toward the substrate.
- Subjects :
- Alkane
chemistry.chemical_classification
Autoxidation
Free Radicals
Molecular Structure
Radical
General Physics and Astronomy
Substrate (chemistry)
Nitroxyl
Photochemistry
Imides
Catalysis
chemistry.chemical_compound
chemistry
Alkanes
Molecule
Reactivity (chemistry)
Nitrogen Oxides
Physical and Theoretical Chemistry
Oxidation-Reduction
Subjects
Details
- ISSN :
- 14639076
- Volume :
- 9
- Issue :
- 6
- Database :
- OpenAIRE
- Journal :
- Physical chemistry chemical physics : PCCP
- Accession number :
- edsair.doi.dedup.....fca842c0767e1afed27446b782af105f