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From Divalent to Pentavalent Iron Imido Complexes and an Fe(V) Nitride via N–C Bond Cleavage

Authors :
Martin Keilwerth
Weiqing Mao
Sergio A. V. Jannuzzi
Liam Grunwald
Frank W. Heinemann
Andreas Scheurer
Jörg Sutter
Serena DeBeer
Dominik Munz
Karsten Meyer
Source :
Journal of the American Chemical Society. 145:873-887
Publication Year :
2022
Publisher :
American Chemical Society (ACS), 2022.

Abstract

As key intermediates in metal-catalyzed nitrogen-transfer chemistry, terminal imido complexes of iron have attracted significant attention for a long time. In search of versatile model compounds, the recently developed second-generation

Details

ISSN :
15205126 and 00027863
Volume :
145
Database :
OpenAIRE
Journal :
Journal of the American Chemical Society
Accession number :
edsair.doi.dedup.....f9a24da30ffaf0274936363a9822891e
Full Text :
https://doi.org/10.1021/jacs.2c09072