Towards Simplifying the Chemistry of N -Acyliminium Ions: A One-Pot Protocol for the Preparation of 5-Acetoxy Pyrrolidin-2-ones and 2-Acetoxy N -Alkoxycarbonyl Pyrrolidines from Imides

Authors :: Mohamed Othman
Raja Ben Othman
Anthony Fousse
Vincent Dalla
Till Bousquet
Fridrich Szemes
Unité de Recherche en Chimie Organique et Macromoléculaire (URCOM)
Université Le Havre Normandie (ULH)
Normandie Université (NU)-Normandie Université (NU)
Source :: SYNTHESIS, SYNTHESIS, Georg Thieme Verlag, 2006, 2006 (05), pp.875-879. ⟨10.1055/s-2006-926318⟩
Publication Year :: 2006
Publisher :: HAL CCSD, 2006.
Abstract: A new one-step protocol for the synthesis of acetoxy lactams starting from imides has been developed. This method involves regiospecific reduction of the imide with LiEt 3 BH, then capture of the transient lithium alkoxide by acetic anhydride.

Language :: German
ISSN :: 00397881 and 1437210X
Database :: OpenAIRE
Journal :: SYNTHESIS, SYNTHESIS, Georg Thieme Verlag, 2006, 2006 (05), pp.875-879. ⟨10.1055/s-2006-926318⟩
Accession number :: edsair.doi.dedup.....f9698ab7343e19509ffe470b093c1c64
Full Text :: https://doi.org/10.1055/s-2006-926318⟩

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