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Diethyl (1-benzyl-4-phenyl-3-trifluoromethyl-1H-pyrrol-2-yl)phosphonate

Authors :
Piotr M. Zagórski
Dariusz Cal
Bartosz Zarychta
Krzysztof Ejsmont
Anna Jezuita
Department of Organic Chemistry, Faculty of Chemistry, University of Lodz, Tamka 12
Faculty of Chemistry, University of Opole, Oleska 48, 45-052 Opole, Poland
Source :
IUCrData, Vol 2, Iss 8, p x171122 (2017)
Publication Year :
2017
Publisher :
International Union of Crystallography, 2017.

Abstract

In the title compound, C22H23F3NO3P, the dihedral angles between the pyrrole ring and the benzyl and phenyl rings are 81.38 (7) and 46.21 (8)°, respectively. The ethyl phosphate groups present with P—O—C—C torsion angles of −178.47 (10) and 106.72 (16)°, and an intramolecular C—H...O hydrogen bond occurs. In the extended structure, molecules are linked by C—H...O and C—H...F hydrogen bonds to generate [001] chains.

Details

Language :
English
ISSN :
24143146
Volume :
2
Issue :
8
Database :
OpenAIRE
Journal :
IUCrData
Accession number :
edsair.doi.dedup.....f8e52de025589b034fef8973918478c0