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Hierarchically porous carbon foams from pickering high internal phase emulsions
- Source :
- CARBON
- Publication Year :
- 2016
- Publisher :
- Elsevier, 2016.
-
Abstract
- Carbon foams were produced from a macroporous poly(divinylbenzene) (poly(DVB) precursor, synthesized by polymerizing the continuous but minority phase of water-in-oil high internal phase emulsions (HIPEs) stabilized by molecular and/or particulate emulsifiers. Both permeable and non-permeable hierarchically porous carbon foams, or ‘carboHIPEs’, were prepared by carbonization of the resulting macroporous polymers at 800 °C. The carbon yields were as high as 26 wt.% of the original polymer. CarboHIPEs retain the pore structure of the macroporous polymer precursor, but with surface areas of up to 505 m2/g and excellent electrical conductivities of 81 S/m. Contrary to some previous reports, the method does not require further modification, such as sulfonation or additional crosslinking of the polyHIPE prior to carbonization, due to the inherently crosslinked structure of poly(DVB). The use of a pourable, aqueous emulsion-template enables simple moulding, minimises waste and avoids the strong acid treatments used to remove many conventional solid-templates. The retention of the macroporous structure is coupled with the introduction of micropores during carbonization, producing hierarchically porous carboHIPEs, suitable for a wide range of applications as sorbents and electrodes.
- Subjects :
- Technology
Materials science
STYRENE
Materials Science
FABRICATION
chemistry.chemical_element
Materials Science, Multidisciplinary
02 engineering and technology
CARBONIZATION
010402 general chemistry
01 natural sciences
09 Engineering
chemistry.chemical_compound
RAMAN-SPECTROSCOPY
Phase (matter)
Polymer chemistry
General Materials Science
TEMPLATES
MONOLITHS
Nanoscience & Nanotechnology
Porosity
DIVINYLBENZENE
chemistry.chemical_classification
IN-OIL EMULSIONS
Aqueous solution
Science & Technology
02 Physical Sciences
Carbonization
Chemistry, Physical
General Chemistry
Polymer
021001 nanoscience & nanotechnology
Divinylbenzene
0104 chemical sciences
Chemistry
chemistry
Chemical engineering
Polymerization
Physical Sciences
MORPHOLOGY
POLYMERS
0210 nano-technology
03 Chemical Sciences
Carbon
Subjects
Details
- Database :
- OpenAIRE
- Journal :
- CARBON
- Accession number :
- edsair.doi.dedup.....f84884d05fdbda1abe103388531ea5c9