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A Diiron Hydrogenase Mimic Featuring a 1,2,3-Triazolylidene
- Source :
- CHIMIA, CHIMIA, Schweizerische Chemische Gesellschaft, 2020, 74 (6), pp.499-503. ⟨10.2533/chimia.2020.499⟩, CHIMIA, Vol 74, Iss 6, Pp 499-503 (2020), CHIMIA, 2020, 74 (6), pp.499-503. ⟨10.2533/chimia.2020.499⟩
- Publication Year :
- 2020
-
Abstract
- A novel complex featuring a mesoionic carbene [Fe2(CO)5(trz)(?-pdt)] (1) (trz = 1-phenyl-l,3-methyl,4-butyl-1,2,3-triazol-5-ylidene), was synthesized and spectroscopically and structurally characterized. The reductive behaviour of this compound in the presence and in the absence of acid (CH3CO2H) was examined by cyclic voltammetry (CV) that revealed the lack of efficient activity towards proton reduction.
- Subjects :
- Proton
010405 organic chemistry
Mesoionic carbene
Mesoionic
proton reductions
General Medicine
General Chemistry
Hydrogenase mimic
[CHIM.INOR]Chemical Sciences/Inorganic chemistry
010402 general chemistry
01 natural sciences
Combinatorial chemistry
Bioinspired model
3. Good health
0104 chemical sciences
lcsh:Chemistry
chemistry.chemical_compound
Proton reduction
chemistry
lcsh:QD1-999
Hydrogenase
[CHIM]Chemical Sciences
Cyclic voltammetry
Diiron complex
Carbene
Subjects
Details
- ISSN :
- 00094293
- Volume :
- 74
- Issue :
- 6
- Database :
- OpenAIRE
- Journal :
- Chimia
- Accession number :
- edsair.doi.dedup.....f82a741956d89c0419c503c0f4276cd5
- Full Text :
- https://doi.org/10.2533/chimia.2020.499⟩