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The tandem intermolecular hydroalkoxylation/claisen rearrangement
- Source :
- Chem. Commun.. 49:4157-4159
- Publication Year :
- 2013
- Publisher :
- Royal Society of Chemistry (RSC), 2013.
-
Abstract
- The Au(I)-catalyzed intermolecular hydroalkoxylation of alkynes with allylic alcohols to provide allyl vinyl ethers that subsequently undergo Claisen rearrangement is reported. This new cascade reaction strategy facilitates the direct formation of γ,δ-unsaturated ketones from simple starting materials in a single step.
- Subjects :
- Allylic rearrangement
Propanols
Stereochemistry
Chemistry
organic chemicals
Intermolecular force
Metals and Alloys
food and beverages
General Chemistry
Ketones
Sigmatropic reaction
Combinatorial chemistry
Catalysis
Carroll rearrangement
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
Claisen rearrangement
Cascade reaction
Alkynes
Materials Chemistry
Ceramics and Composites
Gold
Hydroalkoxylation
Ethers
Subjects
Details
- ISSN :
- 1364548X and 13597345
- Volume :
- 49
- Database :
- OpenAIRE
- Journal :
- Chem. Commun.
- Accession number :
- edsair.doi.dedup.....f6e33a481e4699181cc20f5928fdc0a8
- Full Text :
- https://doi.org/10.1039/c2cc37166a