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Study of Precursor‐Inks Designed for High‐Quality Cu2ZnSnS4 Films for Low‐Cost PV Application
- Publication Year :
- 2019
- Publisher :
- Wiley-VCH Verlag GmbH & Co. KGaA, 2019.
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Abstract
- Kesterite compound Cu2ZnSnS4 is the most promising next leader in the chalcogenide thin films technology as it is based on earth-abundant elements. In this work, kesterite thin films were prepared with a wet chemistry method by using a DMSO solution containing thiourea and acetylacetone, without further addition of vapour sulfur compounds to obtain the Cu2ZnSnS4 phase. The composition and stability of the molecular precursor-ink were investigated by EPR, IR and Raman spectroscopy. Acetate precursors were proved to have a primary role in creating a network in the sol-gel transition by bridging the metals in solution, together with thiourea and DMSO coordination. The high-quality of the thin films, obtained by spin coating deposition and thermal treatment at 500°C, was assessed by XRD, Raman, Energy-Dispersive spectroscopy and optical analysis, which revealed a direct band gap of 1.5 eV. Therefore, the precursor-ink and the deposition process developed in this work are very well suitable for solar cell application.
Details
- Language :
- English
- Database :
- OpenAIRE
- Accession number :
- edsair.doi.dedup.....f51ac316bfe2cd4eea07b983748a608b