Back to Search Start Over

Crystal structure of 2-acetyl-5-(3-methoxyphenyl)-3,7-dimethyl-5H-1,3-thiazolo[3,2-a]pyrimidine-6-carboxylate

Authors :
H. Nagarajaiah
N. L. Prasad
M. S. Krishnamurthy
Noor Shahina Begum
Source :
Acta Crystallographica Section E, Vol 70, Iss 11, Pp o1204-o1204 (2014), Acta Crystallographica Section E: Structure Reports
Publication Year :
2014
Publisher :
International Union of Crystallography (IUCr), 2014.

Abstract

In the title molecule, C20H22N2O4S, the pyrimidine ring is in a flattened half-chair conformation and the 3-methoxyphenyl substituent is in an axial arrangement. The thiazole ring forms a dihedral angle of 81.3 (1)° with the benzene ring. In the crystal, weak C—H...S interactions link molecules into chains along [001]. In addition, there are π–π interactions between inversion-related thiazole rings with a centroid–centroid distance of 3.529 (2) Å. The ethyl group was refined as disordered over two sets of sites with an occupancy ratio of 0.52 (3):0.48 (2).

Details

ISSN :
16005368
Volume :
70
Database :
OpenAIRE
Journal :
Acta Crystallographica Section E Structure Reports Online
Accession number :
edsair.doi.dedup.....f4af3c48ff6846494800f3930434065f