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Synthesis of a molecularly imprinted polymer and its application in selective extraction of fenoprofen from wastewater
- Source :
- Environmental Science and Pollution Research. 25:36724-36735
- Publication Year :
- 2018
- Publisher :
- Springer Science and Business Media LLC, 2018.
-
Abstract
- The presence of various classes of pharmaceutical drugs in different environmental compartments has been reported worldwide. In South Africa, the detection of pharmaceuticals especially the non-steroidal anti-inflammatory drugs is recent, and more studies are being done in order to fully understand their fate in the aquatic environment. With considerations for the need of better sample preparation techniques, this study synthesized a molecularly imprinted polymer for the selective extraction of a non-steroidal anti-inflammatory drug, fenoprofen in aqueous environmental samples. Batch adsorption studies showed that adsorption of fenoprofen onto the cavities of the polymer followed a Langmuir isotherm as well as a pseudo second order model implying formation of a monolayer on the surface through chemisorption. The polymer had a maximum adsorption capacity of 38.8 mg g−1 and a Langmuir surface area of 1607 m2 g−1. The imprinted polymer was then used as the selective sorbent for solid phase extraction in the analysis of fenoprofen from wastewater followed by chromatographic determination. The analytical method gave a detection limit of 0.64 ng mL−1 and recovery of 99.6%. The concentration of fenoprofen detected in influent and effluent samples from two wastewater treatment plants ranged from 24 to 58 ng mL−1. The ability of the treatment plants to remove fenoprofen during wastewater processing based on the difference in concentrations in influent and effluent samples was found to be 41%. This work has shown that there is a possibility of release of fenoprofen from wastewater treatment plants into surface water sources.
- Subjects :
- Langmuir
Polymers
Health, Toxicology and Mutagenesis
Wastewater
010501 environmental sciences
01 natural sciences
Molecular Imprinting
South Africa
symbols.namesake
Adsorption
Limit of Detection
Fenoprofen
medicine
Environmental Chemistry
Solid phase extraction
Effluent
0105 earth and related environmental sciences
Chromatography
Chemistry
Anti-Inflammatory Agents, Non-Steroidal
010401 analytical chemistry
Molecularly imprinted polymer
Langmuir adsorption model
General Medicine
Models, Theoretical
Pollution
0104 chemical sciences
symbols
Water Pollutants, Chemical
medicine.drug
Subjects
Details
- ISSN :
- 16147499 and 09441344
- Volume :
- 25
- Database :
- OpenAIRE
- Journal :
- Environmental Science and Pollution Research
- Accession number :
- edsair.doi.dedup.....f1fba064b021c7a9c5e48b12789d15c4