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Effect of humidity on the composition of isoprene photooxidation secondary organic aerosol

Authors :
Serguei Nizkorodov
Julia Laskin
Tran B. Nguyen
Alexander Laskin
Patrick J. Roach
Source :
Nguyen, T. B; Roach, P. J; Laskin, J.; Laskin, A.; & Nizkorodov, S. A. (2011). Effect of humidity on the composition of isoprene photooxidation secondary organic aerosol. Atmospheric Chemistry and Physics, 11(14), 6931-6944. doi: 10.5194/acp-11-6931-2011. UC Irvine: Retrieved from: http://www.escholarship.org/uc/item/677178jk, Atmospheric Chemistry and Physics, Vol 11, Iss 14, Pp 6931-6944 (2011)
Publication Year :
2011
Publisher :
eScholarship, University of California, 2011.

Abstract

The effect of relative humidity (RH) on the composition and concentrations of gas-phase products and secondary organic aerosol (SOA) generated from the photooxidation of isoprene under high-NOx conditions was investigated. Experiments were performed with hydrogen peroxide as the OH precursor and in the absence of seed aerosol. The relative yields of most gas-phase products were the same regardless of initial water vapor concentration with exception of hydroxyacetone and glycolaldehyde, which were considerably affected by RH. A significant change was observed in the SOA composition, with many unique condensed-phase products formed under humid (90 % RH) vs. dry (

Details

Language :
English
Database :
OpenAIRE
Journal :
Nguyen, T. B; Roach, P. J; Laskin, J.; Laskin, A.; & Nizkorodov, S. A. (2011). Effect of humidity on the composition of isoprene photooxidation secondary organic aerosol. Atmospheric Chemistry and Physics, 11(14), 6931-6944. doi: 10.5194/acp-11-6931-2011. UC Irvine: Retrieved from: http://www.escholarship.org/uc/item/677178jk, Atmospheric Chemistry and Physics, Vol 11, Iss 14, Pp 6931-6944 (2011)
Accession number :
edsair.doi.dedup.....edc5e2dbc14bd9637a3cba95b1aed2b9
Full Text :
https://doi.org/10.5194/acp-11-6931-2011.