Back to Search
Start Over
Effect of humidity on the composition of isoprene photooxidation secondary organic aerosol
- Source :
- Nguyen, T. B; Roach, P. J; Laskin, J.; Laskin, A.; & Nizkorodov, S. A. (2011). Effect of humidity on the composition of isoprene photooxidation secondary organic aerosol. Atmospheric Chemistry and Physics, 11(14), 6931-6944. doi: 10.5194/acp-11-6931-2011. UC Irvine: Retrieved from: http://www.escholarship.org/uc/item/677178jk, Atmospheric Chemistry and Physics, Vol 11, Iss 14, Pp 6931-6944 (2011)
- Publication Year :
- 2011
- Publisher :
- eScholarship, University of California, 2011.
-
Abstract
- The effect of relative humidity (RH) on the composition and concentrations of gas-phase products and secondary organic aerosol (SOA) generated from the photooxidation of isoprene under high-NOx conditions was investigated. Experiments were performed with hydrogen peroxide as the OH precursor and in the absence of seed aerosol. The relative yields of most gas-phase products were the same regardless of initial water vapor concentration with exception of hydroxyacetone and glycolaldehyde, which were considerably affected by RH. A significant change was observed in the SOA composition, with many unique condensed-phase products formed under humid (90 % RH) vs. dry (
- Subjects :
- Atmospheric Science
atmospheric chemistry
alkoxy radicals
h-atom transfer
Inorganic chemistry
alpha-pinene
lcsh:Chemistry
chemistry.chemical_compound
heterogeneous reactions
Physical Sciences and Mathematics
Relative humidity
Hydrogen peroxide
Chemical composition
Isoprene
particulate matter
Glycolaldehyde
Hydroxyacetone
mass-spectrometry
lcsh:QC1-999
Aerosol
lcsh:QD1-999
chemistry
hygroscopic properties
chemical-composition
lcsh:Physics
Water vapor
accretion reactions
Nuclear chemistry
Subjects
Details
- Language :
- English
- Database :
- OpenAIRE
- Journal :
- Nguyen, T. B; Roach, P. J; Laskin, J.; Laskin, A.; & Nizkorodov, S. A. (2011). Effect of humidity on the composition of isoprene photooxidation secondary organic aerosol. Atmospheric Chemistry and Physics, 11(14), 6931-6944. doi: 10.5194/acp-11-6931-2011. UC Irvine: Retrieved from: http://www.escholarship.org/uc/item/677178jk, Atmospheric Chemistry and Physics, Vol 11, Iss 14, Pp 6931-6944 (2011)
- Accession number :
- edsair.doi.dedup.....edc5e2dbc14bd9637a3cba95b1aed2b9
- Full Text :
- https://doi.org/10.5194/acp-11-6931-2011.