Hydro/Deutero Deamination of Arylazo Sulfones under Metal- and (Photo)Catalyst-Free Conditions

Authors :: Carlotta Raviola
Ahmed Anwar Amin
Hawraz Ibrahim M. Amin
Stefano Protti
Barbara Mannucci
Maurizio Fagnoni
Source :: Molecules, Volume 24, Issue 11, Molecules, Vol 24, Iss 11, p 2164 (2019)
Publication Year :: 2019
Publisher :: MDPI, 2019.
Abstract: Hydrodeaminated and monodeuterated aromatics were obtained via a visible-light driven reaction of arylazo sulfones. Deuteration occurs efficiently in deuterated media such as isopropanol-d8 or in THF-d8/water mixtures and exhibits a high tolerance to the nature and the position of the aromatic substituents.

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