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A gold(<scp>i</scp>)-catalyzed substituent-controlled cycloisomerization of propargyl vinyl ethers to multi-substituted furofuran and furopyran derivatives
- Source :
- Chemical Communications. 52:6233-6236
- Publication Year :
- 2016
- Publisher :
- Royal Society of Chemistry (RSC), 2016.
-
Abstract
- A gold(i)-catalyzed substituent-controlled strategy for the stereoselective synthesis of bicyclic furan and pyran derivatives has been developed. The mechanisms of the reactions have been studied thoroughly by deuterium labelling experiments. The applications of the methodologies were demonstrated by evaluating the preliminary anti-fungal activity of the synthetic compounds.
- Subjects :
- Bicyclic molecule
010405 organic chemistry
Metals and Alloys
Substituent
General Chemistry
010402 general chemistry
01 natural sciences
Catalysis
0104 chemical sciences
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
chemistry.chemical_compound
Cycloisomerization
chemistry
Pyran
Furan
Propargyl
Materials Chemistry
Ceramics and Composites
Organic chemistry
Stereoselectivity
Subjects
Details
- ISSN :
- 1364548X and 13597345
- Volume :
- 52
- Database :
- OpenAIRE
- Journal :
- Chemical Communications
- Accession number :
- edsair.doi.dedup.....eaf4cb69cef49f2122fb24a26a3270c7