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Nanoscale distribution of magnetic anisotropies in bimagnetic soft core-hard shell MnFe$_2$O$_4$@CoFe$_2$O$_4$ nanoparticles
- Source :
- Advanced Materials Interfaces, Advanced Materials Interfaces, Wiley, 2017, 4 (22), pp.1700599. ⟨10.1002/admi.201700599⟩
- Publication Year :
- 2016
- Publisher :
- arXiv, 2016.
-
Abstract
- The nanoscale distribution of magnetic anisotropies was measured in core@shell MnFe$_2$O$_4$@CoFe$_2$O$_4$ 7.0 nm particles using a combination of element selective magnetic spectroscopies with different probing depths. As this picture is not accessible by any other technique, emergent magnetic properties were revealed. The coercive field is not constant in a whole nanospinel. The very thin (0.5 nm) CoFe$_2$O$_4$ hard shell imposes a strong magnetic anisotropy to the otherwise very soft MnFe$_2$O$_4$ core: a large gradient in coercivity was measured inside the MnFe$_2$O$_4$ core with lower values close to the interface region, while the inner core presents a substantial coercive field (0.54 T) and a very high remnant magnetization (90% of the magnetization at saturation).<br />Comment: 27 pages (including supporting information)
- Subjects :
- Materials science
RIXS
XAS
Nanoparticle
FOS: Physical sciences
02 engineering and technology
010402 general chemistry
01 natural sciences
Magnetization
RIXS‐MCD
[CHIM]Chemical Sciences
core–shell nanoparticles
Anisotropy
Saturation (magnetic)
Nanoscopic scale
magnetic anisotropy
Condensed Matter - Materials Science
Condensed matter physics
XMCD
Mechanical Engineering
Inner core
Materials Science (cond-mat.mtrl-sci)
[CHIM.MATE]Chemical Sciences/Material chemistry
Coercivity
spinel ferrites
021001 nanoscience & nanotechnology
3. Good health
0104 chemical sciences
Magnetic anisotropy
Mechanics of Materials
0210 nano-technology
Subjects
Details
- ISSN :
- 21967350
- Database :
- OpenAIRE
- Journal :
- Advanced Materials Interfaces, Advanced Materials Interfaces, Wiley, 2017, 4 (22), pp.1700599. ⟨10.1002/admi.201700599⟩
- Accession number :
- edsair.doi.dedup.....eac1b595234a8b6d59248827686e0fe6
- Full Text :
- https://doi.org/10.48550/arxiv.1610.04263