Back to Search Start Over

Nanoscale distribution of magnetic anisotropies in bimagnetic soft core-hard shell MnFe$_2$O$_4$@CoFe$_2$O$_4$ nanoparticles

Authors :
Philippe Sainctavit
Niéli Daffé
Sophie Neveu
Marcin Sikora
Nadejda Bouldi
Véronica Gavrilov
Amélie Juhin
Dario Taverna
Fadi Choueikani
Vincent Dupuis
Mauro Rovezzi
Philippe Ohresser
Marie-Anne Arrio
Alexandre Gloter
Institut de minéralogie, de physique des matériaux et de cosmochimie (IMPMC)
Muséum national d'Histoire naturelle (MNHN)-Institut de recherche pour le développement [IRD] : UR206-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)
Sorbonne Université (SU)
Synchrotron SOLEIL (SSOLEIL)
Centre National de la Recherche Scientifique (CNRS)
AGH University of Science and Technology [Krakow, PL] (AGH UST)
European Synchrotron Radiation Facility (ESRF)
Dispositifs et Instrumentation en Optoélectronique et micro-ondes (DIOM)
Université Jean Monnet [Saint-Étienne] (UJM)
Laboratoire de Physique des Solides (LPS)
Centre National de la Recherche Scientifique (CNRS)-Université Paris-Sud - Paris 11 (UP11)
Source :
Advanced Materials Interfaces, Advanced Materials Interfaces, Wiley, 2017, 4 (22), pp.1700599. ⟨10.1002/admi.201700599⟩
Publication Year :
2016
Publisher :
arXiv, 2016.

Abstract

The nanoscale distribution of magnetic anisotropies was measured in core@shell MnFe$_2$O$_4$@CoFe$_2$O$_4$ 7.0 nm particles using a combination of element selective magnetic spectroscopies with different probing depths. As this picture is not accessible by any other technique, emergent magnetic properties were revealed. The coercive field is not constant in a whole nanospinel. The very thin (0.5 nm) CoFe$_2$O$_4$ hard shell imposes a strong magnetic anisotropy to the otherwise very soft MnFe$_2$O$_4$ core: a large gradient in coercivity was measured inside the MnFe$_2$O$_4$ core with lower values close to the interface region, while the inner core presents a substantial coercive field (0.54 T) and a very high remnant magnetization (90% of the magnetization at saturation).<br />Comment: 27 pages (including supporting information)

Details

ISSN :
21967350
Database :
OpenAIRE
Journal :
Advanced Materials Interfaces, Advanced Materials Interfaces, Wiley, 2017, 4 (22), pp.1700599. ⟨10.1002/admi.201700599⟩
Accession number :
edsair.doi.dedup.....eac1b595234a8b6d59248827686e0fe6
Full Text :
https://doi.org/10.48550/arxiv.1610.04263