Back to Search
Start Over
Recognition of the persistent organic pollutant chlordecone by a hemicryptophane cage
- Source :
- New Journal of Chemistry, New Journal of Chemistry, Royal Society of Chemistry, 2019, 43 (26), pp.10222-10226. ⟨10.1039/c9nj01674k⟩, New Journal of Chemistry, 2019, 43 (26), pp.10222-10226. ⟨10.1039/c9nj01674k⟩
- Publication Year :
- 2019
- Publisher :
- HAL CCSD, 2019.
-
Abstract
- Two molecular cages have been tested as receptors for the persistent organic pollutant chlordecone. Whereas the host bearing amide functions displays a moderate binding constant (126 M−1), the receptor with a tris(2-aminoethyl)amine moiety exhibits a higher association constant (2.1 × 104 M−1). The recognition process was investigated by NMR experiments and DFT calculations.
- Subjects :
- inorganic chemicals
Tris
Persistent organic pollutant
Chemistry
[CHIM.ORGA]Chemical Sciences/Organic chemistry
02 engineering and technology
General Chemistry
010402 general chemistry
021001 nanoscience & nanotechnology
01 natural sciences
Binding constant
Medicinal chemistry
Catalysis
0104 chemical sciences
chemistry.chemical_compound
Amide
Materials Chemistry
Moiety
[CHIM]Chemical Sciences
Amine gas treating
0210 nano-technology
Cage
Receptor
ComputingMilieux_MISCELLANEOUS
Subjects
Details
- Language :
- English
- ISSN :
- 11440546 and 13699261
- Database :
- OpenAIRE
- Journal :
- New Journal of Chemistry, New Journal of Chemistry, Royal Society of Chemistry, 2019, 43 (26), pp.10222-10226. ⟨10.1039/c9nj01674k⟩, New Journal of Chemistry, 2019, 43 (26), pp.10222-10226. ⟨10.1039/c9nj01674k⟩
- Accession number :
- edsair.doi.dedup.....e7c26257a0f40e672126f119bb97d61e