Cyclic ethers to esters and monoesters to bis-esters with unconventional coupling partners under metal free conditions via sp3 C–H functionalisation

Authors :: Srimanta Guin
Ahalya Behera
Ganesh Majji
Bhisma K. Patel
Saroj Kumar Rout
Source :: Chem. Commun.. 50:12193-12196
Publication Year :: 2014
Publisher :: Royal Society of Chemistry (RSC), 2014.
Abstract: An efficient metal free oxidative esterification of sp(3) C-H bonds (adjacent to an oxygen atom) in simple solvents like 1,4-dioxane, tetrahydropyran, tetrahydrofuran and ethyl acetate has been achieved using terminal aryl alkenes and alkynes as the ArCOO(-) sources.

Subjects :: Aryl
Metals and Alloys
Ethyl acetate
General Chemistry
Tetrahydropyran
Catalysis
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
chemistry.chemical_compound
Oxygen atom
chemistry
Metal free
Polymer chemistry
Materials Chemistry
Ceramics and Composites
Organic chemistry
Tetrahydrofuran

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