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Molecular tectonics: dimensionality and geometry control of silver coordination networks based on pyrazolyl appended thiacalixarenes
- Source :
- CrystEngComm, CrystEngComm, Royal Society of Chemistry, 2016, 18 (5), pp.691-703. ⟨10.1039/C5CE02310F⟩
- Publication Year :
- 2016
- Publisher :
- HAL CCSD, 2016.
-
Abstract
- International audience; Combinations of six new coordinating tectons (3-8) tetrakis-pyrazolyl appended calix[4]arenes, blocked in 1,3-A conformation, based on 1 (tetrathiacalix[4]arene) and 2 (tetrathiatetramercaptocalix[4]arene) derivatives, with AgX salts (X = NO3-, BF4-, XF6-(X = P, As and Sb)) lead to nine new silver coordination networks. The flexible nature of tectons 3-8 (length of the spacer between the macrocycle and the pyrazolyl coordinating unit), their high number of potential coordinating sites and the loose coordination demand of Ag + cation lead to the formation of a large variety of networks with different dimensionality: from 1D (5-AgSbF6, 5-AgBF4, 7-AgSbF6 and 8-AgNO3) to extended 2D (6-AgBF4 and 8-AgSbF6) and to a series of three isostructural porous diamond-like 3D architectures (6-AgXF6 (X = P, As and Sb)).
- Subjects :
- 010405 organic chemistry
Chemistry
Stereochemistry
General Chemistry
010402 general chemistry
Condensed Matter Physics
01 natural sciences
0104 chemical sciences
Crystallography
[CHIM]Chemical Sciences
General Materials Science
[CHIM.COOR]Chemical Sciences/Coordination chemistry
Isostructural
Curse of dimensionality
Subjects
Details
- Language :
- English
- ISSN :
- 14668033
- Database :
- OpenAIRE
- Journal :
- CrystEngComm, CrystEngComm, Royal Society of Chemistry, 2016, 18 (5), pp.691-703. ⟨10.1039/C5CE02310F⟩
- Accession number :
- edsair.doi.dedup.....e6461a5fbde0fa5a709e4a30e85a4bec