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Diaquabis(5-carboxy-2-propyl-1H-imidazole-4-carboxylato-κ2 N 3,O 4)cadmium(II) 3.5-hydrate
- Source :
- Acta Crystallographica Section E: Structure Reports
- Publication Year :
- 2010
- Publisher :
- International Union of Crystallography, 2010.
-
Abstract
- In the title complex, [Cd(C(8)H(9)N(2)O(4))(2)(H(2)O)(2)]·3.5H(2)O, the Cd(II) is coordinated by two water mol-ecules and N,O-chelated by two 5-carb-oxy-2-propyl-1H-imidazole-4-carboxyl-ate anions in a distorted octa-hedral geometry. The two imidazole rings are oriented to each other with a dihedral angle of 75.1 (2)°. Strong O-H⋯O hydrogen bonds between protonated and deprotonated carboxyl-ate groups occur in the mol-ecular structure. In the crystal structure extensive O-H⋯O and N-H⋯O hydrogen bonds help to stabilize the three-dimensional supra-molecular framework. The propyl groups of anions are disordered over two sites with refined occupancies of 0.768 (6):0.232 (6) and 0.642 (8):0.358 (8).
Details
- Language :
- English
- ISSN :
- 16005368
- Volume :
- 66
- Issue :
- Pt 9
- Database :
- OpenAIRE
- Journal :
- Acta Crystallographica Section E: Structure Reports Online
- Accession number :
- edsair.doi.dedup.....e550cccb10d71b6a72e42212f799e1a6