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Inexpensive and bench stable diarylmethylium tetrafluoroborates as organocatalysts in the light mediated hydrosulfonylation of unactivated alkenes

Authors :
Polyssena Renzi
Emanuele Azzi
Sylvain Ascensio
Stefano Parisotto
Fabrizio Sordello
Francesco Pellegrino
Giovanni Ghigo
Annamaria Deagostino
Source :
Chemical Science. 14:2721-2734
Publication Year :
2023
Publisher :
Royal Society of Chemistry (RSC), 2023.

Abstract

Can a cheap and bench stable salt catalyse the hydrosulfonylation of unactivated alkenes? Yes it does! Just mix a diarylmethylium tetrafluoroborate salt with a sulfinate salt, wait for the formation of the adduct and turn purple light on it.

Subjects

Subjects :
General Chemistry

Details

ISSN :
20416539 and 20416520
Volume :
14
Database :
OpenAIRE
Journal :
Chemical Science
Accession number :
edsair.doi.dedup.....e44e609e375e7ce22b51a5b8b2aff8f3
Full Text :
https://doi.org/10.1039/d3sc00182b