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Selective conversion of 5-hydroxymethylfurfural to diketone derivatives over Beta zeolite-supported Pd catalysts in water
- Source :
- JOURNAL OF CATALYSIS
- Publication Year :
- 2019
- Publisher :
- Elsevier BV, 2019.
-
Abstract
- Conversion of 5-hydroxymethylfurfural (HMF) in water to the linear diketone derivatives 1-hydroxyhexane-2,5-dione (HHD) and 2,5-hexanedione (HXD) was investigated over a series of Beta zeolite-supported transition metal catalysts (Co, Ni, Cu, Ru, Pd). Their catalytic performance was tested in a batch stirred reactor (T = 110 °C, PH2 = 20 bar) with Pd showing the highest activity and selectivity to HHD and HXD. The effects of Pd particle size, zeolite Si/Al ratio and reaction conditions (T = 80–155 °C, PH2 = 5–60 bar) were also investigated. The incorporation of Pd into Beta zeolite by the deposition-coprecipitation method produced the most efficient catalyst, affording complete HMF conversion (T = 110 °C, PH2 = 60 bar) predominantly to HHD (68% selectivity) and HXD (8% selectivity). The combination of a bifunctional acid/redox solid catalyst and water enhances the hydrolytic ring-opening and subsequent hydrogenation of the furan ring. Catalytic activity can be partially restored by a simple regeneration treatment. This work establishes a catalytic route to produce valuable diketone derivatives from renewable furanic platform sources in water.
Details
- ISSN :
- 00219517
- Volume :
- 375
- Database :
- OpenAIRE
- Journal :
- Journal of Catalysis
- Accession number :
- edsair.doi.dedup.....e44d6fcc215a7caf388d13ea5992f80d