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Bis(alkoxycarbonyl) complexes of platinum: preparation, reactivity and their role in carbonylation reactions
- Source :
- Journal of Organometallic Chemistry. 481:173-178
- Publication Year :
- 1994
- Publisher :
- Elsevier BV, 1994.
-
Abstract
- bis(alkoxycarbonyl) complexes of platinum of the type [Pt(COOR)2L] [L = 1,2-bis(diphenylphosphino)ethane (dppe), 1,3-bis(diphenylphosphino)propane (dppp), l,4-bis(diphenylphosphino)butane (dppb), 1,1'-bis(diphenylphosphino)ferrocene (dppf) or 1,2-bis-(diphenylphosphino)benzene (dpb); R = CH3, C6H5 or C2H5] were obtained by reaction of [PtCl2L] with carbon monoxide and alkoxides. Palladium and nickel complexes gave only carbonyl complexes of the type [M(CO)L] or [M(CO)2L]. The new complexes were characterized by chemical and spectroscopic means. The X-ray structure of [Pt(COOCH3)2(dppf] · CH3OH is also reported. The reactivity of some alkoxycarbonyl complexes was also investigated.
- Subjects :
- Organic Chemistry
chemistry.chemical_element
Carbonylation
Biochemistry
Medicinal chemistry
Inorganic Chemistry
chemistry.chemical_compound
Nickel
Platinum
Phosphine
X-ray structure
Alkoxycarbonyls
chemistry
Ferrocene
Materials Chemistry
Organic chemistry
Reactivity (chemistry)
Physical and Theoretical Chemistry
Palladium
Carbon monoxide
Subjects
Details
- ISSN :
- 0022328X
- Volume :
- 481
- Database :
- OpenAIRE
- Journal :
- Journal of Organometallic Chemistry
- Accession number :
- edsair.doi.dedup.....e3707cdfe62aba1c5834a8dd1624c4e8