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The role of water and influence of hydrogen bonding on the self-assembly aggregation induced emission of an anthracene-guanidine-derivative

Authors :
Andrés Garzón-Ruiz
Boiko Cohen
Carlos Alonso-Moreno
Daniel Hermida-Merino
José Albaladejo
Mark Van der Auweraer
Alberto Juan
Cristina Martin
Iván Bravo
Pedro J. Pacheco-Liñán
Biomolecular Nanotechnology
Source :
Chemical communications, 56(29), 4102-4105. Royal Society of Chemistry
Publication Year :
2020

Abstract

We report a luminescent anthracene-guanidine derivative that forms rare T-shape dimers, resulting in an excimer with a quantum yield approaching one. Water plays a fundamental role through H-bonding guiding the self-assembly. These results establish a new framework for environmentally friendly aggregation-induced emission luminogens.

Details

ISSN :
1364548X and 13597345
Volume :
56
Issue :
29
Database :
OpenAIRE
Journal :
Chemical communications (Cambridge, England)
Accession number :
edsair.doi.dedup.....e30af8402f976c5b0a85249b6c7c74e3