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Novel Approach for the Stereocontrolled Construction of Eudesmane Skeleton: A Concise Synthesis of (±)-Balanitol
- Source :
- Organic Letters. 3:2555-2557
- Publication Year :
- 2001
- Publisher :
- American Chemical Society (ACS), 2001.
-
Abstract
- [structure: see text] A novel method for the stereocontrolled construction of the eudesmane ring system based on a cationic cyclization is presented, and the approach is exemplified in a short and efficient total synthesis of (+/-)-balanitol (2).
- Subjects :
- Plants, Medicinal
Chemistry
Stereochemistry
Organic Chemistry
Molecular Conformation
Cationic polymerization
Total synthesis
Stereoisomerism
Naphthalenes
Skeleton (category theory)
Ring (chemistry)
Biochemistry
Catalysis
Molecular conformation
Japan
Cyclization
Sesquiterpenes, Eudesmane
Indicators and Reagents
Hydrogenation
Physical and Theoretical Chemistry
Sesquiterpenes
Subjects
Details
- ISSN :
- 15237052 and 15237060
- Volume :
- 3
- Database :
- OpenAIRE
- Journal :
- Organic Letters
- Accession number :
- edsair.doi.dedup.....e280e11c524fa17358c9514af5d99147
- Full Text :
- https://doi.org/10.1021/ol016230f