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Metal free synthesis of homoallylic alcohols promoted by ultrasound

Authors :
Paulo H. Menezes
TĂșlio R. Couto
Italo H. Cavalcanti
Juliano Carlo Rufino Freitas
Roberta A. Oliveira
Jucleiton J. R. Freitas
Source :
Ultrasonics Sonochemistry. 21:1609-1614
Publication Year :
2014
Publisher :
Elsevier BV, 2014.

Abstract

The use of ultrasound irradiation to promote the allylation of aldehydes containing different functionalities with potassium allyltrifluoroborates is described. The method features the use of a minimum amount of acetone as solvent, without any other catalyst or promoter. The products were obtained in high yields, short reaction times, at room temperature and without the need of further purification.

Details

ISSN :
13504177
Volume :
21
Database :
OpenAIRE
Journal :
Ultrasonics Sonochemistry
Accession number :
edsair.doi.dedup.....e2724067022350eb7a11b4acc36ecd18
Full Text :
https://doi.org/10.1016/j.ultsonch.2014.04.001