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Sulfate encapsulation in a metal-assisted capsule based on a mono-pyridylurea ligand

Authors :
Shaoguang Li
Zaiwen Yang
Chuandong Jia
Xiaojuan Huang
Yana Xia
Yanyan Liu
Biao Wu
Xiao-Juan Yang
Source :
Chemical Communications. 47:2880
Publication Year :
2011
Publisher :
Royal Society of Chemistry (RSC), 2011.

Abstract

A sulfate-encapsulating complex, [Cu(1)L(6)]·3[Cu(2)L(2)(DMF)(4)](SO(4))(4) (1, L = N-(1-naphthyl)-N'-(3-pyridyl)urea) is synthesized in which two C(3)-clefts of the octahedral complexes interdigitate to form a cavity to encapsulate the sulfate ion by six urea groups.

Details

ISSN :
1364548X and 13597345
Volume :
47
Database :
OpenAIRE
Journal :
Chemical Communications
Accession number :
edsair.doi.dedup.....e172aaed3cfc3c5d5fa8335f85e0809b