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Can the glass transition be explained without a growing static length scale?

Authors :
Gilles Tarjus
Giulio Biroli
Ludovic Berthier
Jean-Philippe Bouchaud
Laboratoire Charles Coulomb (L2C)
Université de Montpellier (UM)-Centre National de la Recherche Scientifique (CNRS)
Laboratoire de Physique Statistique de l'ENS (LPS)
Fédération de recherche du Département de physique de l'Ecole Normale Supérieure - ENS Paris (FRDPENS)
École normale supérieure - Paris (ENS Paris)
Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Centre National de la Recherche Scientifique (CNRS)-École normale supérieure - Paris (ENS Paris)
Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Centre National de la Recherche Scientifique (CNRS)-Université Paris Diderot - Paris 7 (UPD7)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)
Systèmes Désordonnés et Applications
Laboratoire de physique de l'ENS - ENS Paris (LPENS (UMR_8023))
Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Centre National de la Recherche Scientifique (CNRS)-Sorbonne Université (SU)-Université Paris Diderot - Paris 7 (UPD7)-École normale supérieure - Paris (ENS Paris)
Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Centre National de la Recherche Scientifique (CNRS)-Sorbonne Université (SU)-Université Paris Diderot - Paris 7 (UPD7)
Source :
Journal of Chemical Physics, Journal of Chemical Physics, American Institute of Physics, 2019, 150, pp.094501. ⟨10.1063/1.5086509⟩
Publication Year :
2019
Publisher :
HAL CCSD, 2019.

Abstract

It was recently discovered that SWAP, a Monte Carlo algorithm that involves the exchange of pairs of particles of differing diameters, can dramatically accelerate the equilibration of simulated supercooled liquids in regimes where the normal dynamics is glassy. This spectacular effect was subsequently interpreted as direct evidence against a static, cooperative explanation of the glass transition such as the one offered by the random first-order transition (RFOT) theory. We review several empirical facts that support the opposite view, namely, that a local mechanism cannot explain the glass transition phenomenology. We explain the speedup induced by SWAP within the framework of the RFOT theory. We suggest that the efficiency of SWAP stems from a postponed onset of glassy dynamics, which allows the efficient exploration of configuration space even in the regime where the physical dynamics is dominated by activated events across free-energy barriers. We describe this effect in terms of `crumbling metastability' and use the example of nucleation to illustrate the possibility of circumventing free-energy barriers of thermodynamic origin by a change of the local dynamical rules.<br />Comment: 15 pages, 3 figures; v2: improved discussions and clarifications

Details

Language :
English
ISSN :
00219606 and 10897690
Database :
OpenAIRE
Journal :
Journal of Chemical Physics, Journal of Chemical Physics, American Institute of Physics, 2019, 150, pp.094501. ⟨10.1063/1.5086509⟩
Accession number :
edsair.doi.dedup.....e0cd158bf7a6e77fd20576a831f64c27