Free-standing iridium and rhodium-based hierarchically-coiled ultrathin nanosheets for highly selective reduction of nitrobenzene to azoxybenzene under ambient conditions

The fabrication of atom-layered two dimensional (2D) noble metal nanosheets (NSs) in a face-centered cubic (fcc) structure is of broad scientific and technological importance, yet this remains a challenge due to the intrinsic cubic symmetry and high surface energy of fcc noble metals. Herein, we report a solid-liquid interface mediated 2D growth method towards the synthesis of hierarchically-coiled ultrathin Ir NSs (thickness