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Static and Dynamic Bethe-Salpeter Equations in the $T$-Matrix Approximation
- Source :
- Journal of Chemical Physics, Journal of Chemical Physics, 2022, 156 (16), pp.164101. ⟨10.1063/5.0088364⟩
- Publication Year :
- 2022
- Publisher :
- HAL CCSD, 2022.
-
Abstract
- While the well-established $GW$ approximation corresponds to a resummation of the direct ring diagrams and is particularly well suited for weakly-correlated systems, the $T$-matrix approximation does sum ladder diagrams up to infinity and is supposedly more appropriate in the presence of strong correlation. Here, we derive and implement, for the first time, the static and dynamic Bethe-Salpeter equations when one considers $T$-matrix quasiparticle energies as well as a $T$-matrix-based kernel. The performance of the static scheme and its perturbative dynamical correction are assessed by computing the neutral excited states of molecular systems. Comparison with more conventional schemes as well as other wave function methods are also reported. Our results suggest that the $T$-matrix-based formalism performs best in few-electron systems where the electron density remains low.<br />Comment: 10 pages, 6 figures
- Subjects :
- Chemical Physics (physics.chem-ph)
Condensed Matter - Materials Science
Nuclear Theory
Strongly Correlated Electrons (cond-mat.str-el)
General Physics and Astronomy
Materials Science (cond-mat.mtrl-sci)
FOS: Physical sciences
Computational Physics (physics.comp-ph)
Nuclear Theory (nucl-th)
[CHIM.THEO]Chemical Sciences/Theoretical and/or physical chemistry
Condensed Matter - Strongly Correlated Electrons
Physics - Chemical Physics
Physical and Theoretical Chemistry
Physics - Computational Physics
Subjects
Details
- Language :
- English
- ISSN :
- 00219606 and 10897690
- Database :
- OpenAIRE
- Journal :
- Journal of Chemical Physics, Journal of Chemical Physics, 2022, 156 (16), pp.164101. ⟨10.1063/5.0088364⟩
- Accession number :
- edsair.doi.dedup.....e00bb0b00ccaecf8cbb4d78c93047e27