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Gels of shape-persistent macrocycles: the role of the interior

Authors :
Thomas Prangenberg
Joscha Vollmeyer
Werner Mader
Sigurd Höger
Stefan-S. Jester
Friederike Eberhagen
Source :
Chemical Communications. 48:6547
Publication Year :
2012
Publisher :
Royal Society of Chemistry (RSC), 2012.

Abstract

The aggregation of shape-persistent macrocycles with an empty cavity, an undecyldiether strand and a tetraethylene glycol strand leads in all cases to a macroscopic gelation of the solvent. However, the gelation temperatures are fine-tuned by the intraannular substituents.

Subjects

Subjects :
Tetraethylene glycol
Solvent
Crystallography
Chemistry
Polymer chemistry
Materials Chemistry
Metals and Alloys
Ceramics and Composites
General Chemistry
Catalysis
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials

Details

ISSN :
1364548X and 13597345
Volume :
48
Database :
OpenAIRE
Journal :
Chemical Communications
Accession number :
edsair.doi.dedup.....dd1205356f2a25972d63a8e74c11c900

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