An experimental comparison: Horizontal evaluation of valuable metal extraction and arsenic emission characteristics of tailings from different copper smelting slag recovery processes

This study comprehensively investigated arsenic's enrichment, distribution, and characteristics in tailings. XRD and SEM-EDS characterized the phase and morphology of tailings from various smelting processes. At the same time, the embedding characteristics of arsenic in the ore phase were analyzed by EPMA. The differences between arsenic's leading ore phase carriers in different recovery processes were found. It was discussed that this phenomenon would be related to the element-binding ability and the precipitation priority of the ore phase. The occurrence state of arsenic was discussed by sequential chemical extraction experiments. The proportion of leachable arsenic is higher than the low-risk limit, whatever which smelting method is adopted, which leads to high environmental risk. In the experiment of comparing the leaching toxicity of tailings by different leaching methods, the arsenic concentration in the leaching solution of tailings recovered by the flotation method exceeds the specified safety range. Although the tailings after reduction smelting did not show high leaching toxicity, a large number of accumulations also would not represent absolute safety.