Sub-lattice of Jahn-Teller centers in hexaferrite crystal

A novel type of sub-lattice of the Jahn-Teller (JT) centers was arranged in Ti-doped barium hexaferrite BaFe12O19. In the un-doped crystal all iron ions, sitting in five different crystallographic positions, are Fe3+ in the high-spin configuration (S = 5/2) and have a non-degenerate ground state. We show that the electron-donor Ti substitution converts the ions to Fe2+ predominantly in tetrahedral coordination, resulting in doubly-degenerate states subject to the E⊗ e problem of the JT effect. The arranged JT complexes, Fe2+O4, their adiabatic potential energy, non-linear and quantum dynamics, have been studied by means of ultrasound and terahertz-infrared spectroscopies. The JT complexes are sensitive to external stress and applied magnetic field. For that reason, the properties of the doped crystal can be controlled by the amount and state of the JT complexes. © 2020, The Author(s). Deutscher Akademischer Austauschdienst, DAAD Russian Foundation for Basic Research, RFBR: 18–02–00332 a Deutscher Akademischer Austauschdienst, DAAD: 91728513 Ministry of Education and Science of the Russian Federation, Minobrnauka: 19–53–04010 19–72–00055 Ministry of Education and Science of the Russian Federation, Minobrnauka The authors acknowledge fruitful discussions with A.S. Prokhorov. We acknowledge support of the HLD at HZDR, member of the European Magnetic Field Laboratory (EMFL). At Ural Federal University, the research was supported by the Russian Foundation for Basic Research (18–02–00332 a), UrFU Center of Excellence “Radiation and Nuclear Technologies” (Competitiveness Enhancement Program), the Ministry of Education and Science of the Russian Federation (Program 5–100). In M.N. Miheev Institute of Metal Physics, the research was carried out within the state assignment of the Ministry of Education and Science of the Russian Federation (theme “Electron” No. AAAA-A18–118020190098–5. At South Ural State University, the authors were generally supported by Act 211 Government of the Russian Federation, contract № 02.A03.21.0011. The single crystal growth part was supported by Russian Foundation for Basic Research (19–53–04010). At Moscow Institute of Physics and Technology, the work was supported by the Russian Ministry of Education and Science (Program 5–100) and by the German Academic Exchange Service (DAAD) Michael Lomonosov Programm Linie B, 91728513. Time-domain low temperature spectroscopic experiments were financially supported by the Russian Scientific Foundation (19–72–00055).