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Palladium-Catalyzed Alkenylation of Ketone Enolates under Mild Conditions
- Source :
- Organic Letters. 16:3970-3973
- Publication Year :
- 2014
- Publisher :
- American Chemical Society (ACS), 2014.
-
Abstract
- A protocol for a mild, catalytic, intermolecular alkenylation of ketone enolates has been developed using a Pd/Q-Phos catalyst. Efficient intermolecular coupling of a variety of ketones with alkenyl bromides was achieved with a slight excess of LiHMDS and temperatures down to 0 °C.
- Subjects :
- chemistry.chemical_classification
Ketone
Molecular Structure
Organic Chemistry
Intermolecular force
chemistry.chemical_element
Alkenes
Ketones
Biochemistry
Medicinal chemistry
Catalysis
Hydrocarbons, Brominated
chemistry
Combinatorial Chemistry Techniques
Organic chemistry
Physical and Theoretical Chemistry
Palladium
Subjects
Details
- ISSN :
- 15237052 and 15237060
- Volume :
- 16
- Database :
- OpenAIRE
- Journal :
- Organic Letters
- Accession number :
- edsair.doi.dedup.....da3f93400a4d33ee6b5f3c34381d883d