Copper-Catalyzed Regioselective Sila-Acylation and Silaformylation of 1,3-Dienes Using Esters

The regioselective sila-acylation and silaformylation of 1,3-dienes was achieved over a copper catalyst using a silylborane as a silyl source. β,γ-Unsaturated ketones with a (dimethylphenylsilyl)methyl moiety at the α-position were obtained using esters, while β,γ-unsaturated aldehydes were obtained using formate esters.