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An inorganic–organic composite framework with an unprecedented 3D heterometallic inorganic connectivity and white-light emission

Authors :
Huabin Zhang
Qipeng Li
Ping Lin
Xiao-Chen Shan
Shao-Wu Du
Fenglei Du
Source :
Chemical Communications. 49:2231
Publication Year :
2013
Publisher :
Royal Society of Chemistry (RSC), 2013.

Abstract

The first example of an inorganic-organic composite framework with a 3D inorganic Cd-O-M (M = Cd, Rb) connectivity, featuring a unique {Cd(7)Rb}(n) helix and nanoscale {Cd(16)Rb(4)} and {Cd(18)Rb(2)} rings, has been constructed and structurally characterized. This compound exhibits white-light emission and a wavelength-dependent photochromic response.

Details

ISSN :
1364548X and 13597345
Volume :
49
Database :
OpenAIRE
Journal :
Chemical Communications
Accession number :
edsair.doi.dedup.....d961f0e8718487e484862e588d42f1f8