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The nematic dumbbell model

Authors :
G. Marrucci
Pier Luca Maffettone
Maffettone, PIER LUCA
Marrucci, G.
Source :
Journal of Rheology. 36:1547-1561
Publication Year :
1992
Publisher :
Society of Rheology, 1992.

Abstract

Flexible polymeric chains (Kuhn chains) made up of nematogenic moieties are considered here. The simplest approach to the dynamics of such a system, in both the isotropic and the nematic phases, is that of modeling the chain as an elastic dumbbell where the ‘‘spring’’ law also accounts for the nematic interaction. The constitutive equation of this ‘‘nematic dumbbell model’’ is thereby derived. The rheological predictions so obtained are qualitatively compared with the most prominent features of LCP rheology as well as with previous theoretical results.

Details

ISSN :
15208516 and 01486055
Volume :
36
Database :
OpenAIRE
Journal :
Journal of Rheology
Accession number :
edsair.doi.dedup.....d6ab0413e458898a5145c75919334c03