Efficient optical resolution of water-soluble self-assembled tetrahedral M4L6 cages with 1,1′-bi-2-naphthol

Authors :: Shigang Wan
Li-Li Zeng
Li-Rong Lin
Yiji Lin
Hui Zhang
Source :: Chem. Commun.. 50:15301-15304
Publication Year :: 2014
Publisher :: Royal Society of Chemistry (RSC), 2014.
Abstract: In this paper, a water-soluble racemic self-assembled tetrahedral cage [Fe4L6](4-) was successfully resolved into their ΔΔΔΔ and ΛΛΛΛ enantiomers by (R)-/(S)-1,1'-bi-2-naphthol. The enantiomeric excess of the resolved Fe(II) cage was 99%.

Subjects :: Chemistry
1,1'-Bi-2-naphthol
Resolution (electron density)
Metals and Alloys
General Chemistry
Catalysis
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
Self assembled
chemistry.chemical_compound
Crystallography
Water soluble
Materials Chemistry
Ceramics and Composites
Tetrahedron
Enantiomer
Enantiomeric excess

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