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A macrocyclic tetranuclear ZnII complex as a receptor for selective dual fluorescence sensing of F− and AcO−: effect of a macrocyclic ligand
- Source :
- New Journal of Chemistry. 43:13152-13161
- Publication Year :
- 2019
- Publisher :
- Royal Society of Chemistry (RSC), 2019.
-
Abstract
- A 48-membered macrocyclic ZnII-Schiff base complex DAS (Dual Anion Sensor) containing protonated imine has been synthesized and characterised. The single crystal X-ray structural analysis reveals a tetranuclear complex cation [Zn4(LH3)(NO3)5]2+ counterbalanced by a [Zn(NO3)4]2− anion. DAS acts as a dual anion sensor which can selectively detect fluoride and acetate in aqueous methanolic solution by change in UV-vis spectra as well as by fluorescence enhancement. A probable mechanistic pathway has been proposed and DFT calculations corroborate well with the experimental data. The calculated limit of detection for F− and AcO− ions was 0.18 and 1.98 μM, and 0.15 and 1.8 μM from UV and FL data, respectively. Interestingly, DAS behaves as an INHIBIT logic gate with F−/AcO− and H+ as inputs. To the best of our knowledge, this is the first example where a macrocyclic Zn-complex serves as an INHIBIT logic gate. Practical utility of DAS has been explored by successful detection of F− in commercially available toothpaste as well as solid state detection of F− and AcO−.
- Subjects :
- MECHANISM
Chemistry, Multidisciplinary
Imine
Protonation
02 engineering and technology
010402 general chemistry
ANTHRACENE
01 natural sciences
AQUEOUS-SOLUTION
Catalysis
ANION RECOGNITION
chemistry.chemical_compound
BINDING
Materials Chemistry
PROBE
FLUORIDE IONS
Detection limit
Science & Technology
Aqueous solution
SENSOR
General Chemistry
021001 nanoscience & nanotechnology
Combinatorial chemistry
Fluorescence
0104 chemical sciences
Chemistry
chemistry
PORPHYRIN
Physical Sciences
CHEMOSENSOR
Macrocyclic ligand
0210 nano-technology
Single crystal
Fluoride
Subjects
Details
- ISSN :
- 13699261 and 11440546
- Volume :
- 43
- Database :
- OpenAIRE
- Journal :
- New Journal of Chemistry
- Accession number :
- edsair.doi.dedup.....d4c19e373bb1bc80d8094dc2b0415627